首页   按字顺浏览 期刊浏览 卷期浏览 An Infrared Spectroscopic Study ofp-n-Alkoxybenzoic Acids
An Infrared Spectroscopic Study ofp-n-Alkoxybenzoic Acids

 

作者: Paul Painter,   Chris Cleveland,   Mike Coleman,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  (Taylor Available online 2000)
卷期: Volume 348, issue 1  

页码: 269-293

 

ISSN:1058-725X

 

年代: 2000

 

DOI:10.1080/10587250008024811

 

出版商: Taylor & Francis Group

 

关键词: Order/Disorder;Carbonyl Splitting Stretching Vibrations;Crystallin/LC Forms

 

数据来源: Taylor

 

摘要:

The infrared spectra of variousp-n-alkoxybenzoic acids are reported. The carbonyl stretching region of these materials is surprisingly sensitive to packing within the various crystal forms, a consequence of the sensitivity of these modes to hydrogen bonding and transition dipole coupling. The isotypic crystal form found in those acids with n>6 are characterized by a splitting in the carboxyl C=O stretching region, a consequence of interactions between the disordered arrangement of carboxyl groups from layer to layer. This splitting is not observed in those alkoxybenzoic acids where n<7. The infrared spectra also show that there is a solid state transformation from the crystalline state to conformationally disordered or ``condis” crystals as intermediates between the crystalline and liquid crystalline forms.

 

点击下载:  PDF (813KB)



返 回