Chromatographic Determination of the Relative Retention of Isotopic Species of Oxygen in Methanol and Methan-d3-ol
作者:
R.E. Pauls,
N.H. Mahle,
A.T. Shepard,
JennyChow Gaw,
L.B. Rogers,
期刊:
Separation Science
(Taylor Available online 1977)
卷期:
Volume 12,
issue 3
页码: 307-320
ISSN:0037-2366
年代: 1977
DOI:10.1080/00372367708058079
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A high-precision gas chromatograph was used in conjunction with a quadrupole mass filter and an on-line computer to study the fractionation of oxygen isotopes by Porapak T and glycerol in CH3OH and CD3OH as a function of temperature. Values of relative retention on the order of 1.002 compared favorably with results for the vapor pressure ratio obtained by classical means. Differences from unity were much smaller for the activity-coefficient ratio than for the vapor-pressure ratio. Differential thermodynamic data were also reported.
点击下载:
PDF (618KB)
返 回