Patternwise esterification at room temperature: A novel wet and dry developable, deep ultraviolet photoresist
作者:
C. M. J. Mutsaers,
W. P. M. Nijssen,
F. A. Vollenbroek,
P. A. Kraakman,
期刊:
Journal of Vacuum Science&Technology B: Microelectronics and Nanometer Structures Processing, Measurement, and Phenomena
(AIP Available online 1992)
卷期:
Volume 10,
issue 2
页码: 729-734
ISSN:1071-1023
年代: 1992
DOI:10.1116/1.586438
出版商: American Vacuum Society
关键词: PHOTORESISTS;ULTRAVIOLET RADIATION;LITHOGRAPHY;ESTERIFICATION;PHOTOCHEMICAL REACTIONS;MEDIUM TEMPERATURE
数据来源: AIP
摘要:
A deep ultraviolet photoresist based on 1,1’(dodecamethylene)bis(3‐diazo‐2,4‐piperidinedione) and poly(3‐methyl‐4‐hydroxystyrene) can be esterified at room temperature if the ultraviolet exposure is performed in a dry environment. No water‐free bake treatment during or after the exposure is necessary to obtain a high degree of esterification, as in the case of conventional diazonaphthoquinone/novolak based photoresists. Patternwise esterification results in 0.45 and 0.35 μm lines and spaces in the wet developable image reversal and the dry developable submicron positive dry etch resist process, respectively, using a 248 nm contact exposure.
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