Adsorption of ethyl alcohol on silica gel
作者:
Shinobu Masamune,
J. M. Smith,
期刊:
AIChE Journal
(WILEY Available online 1965)
卷期:
Volume 11,
issue 1
页码: 41-45
ISSN:0001-1541
年代: 1965
DOI:10.1002/aic.690110112
出版商: American Institute of Chemical Engineers
数据来源: WILEY
摘要:
AbstractThis work utilizes the developments of the foregoing paper (10) to analyze adsorption data, in the form of breakthrough curves, for ethyl alcohol on silica gel at 90° to 155°C. It was found that for the smallest particle size, and in the lower part of the temperature range, the overall rate was determined by the surface adsorption process. At other conditions intraparticle diffusion was also a significant resistance in the overall process. The theoretical breakthrough curves agreed well with the experimental ones, so that the surface rate constant and diffusivity could be calculated.Analysis of the diffusivity results showed that surface migration on the pore walls was the predominant contribution rather than gas‐phase diffusion in the pore vol
点击下载:
PDF
(532KB)
返 回