Broadband dielectric spectroscopy on ferroelectric liquid-crystalline side group polymers
作者:
S.U. Vallerien,
F. Kremer,
G. Scherowsky,
A. Schliwa,
K. Kühnpast,
E.W. Fischer,
期刊:
Liquid Crystals
(Taylor Available online 1990)
卷期:
Volume 8,
issue 5
页码: 719-725
ISSN:0267-8292
年代: 1990
DOI:10.1080/02678299008047383
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Broadband dielectric spectroscopy (10−1to 107Hz, 100 to 450 K) has been applied, for the first time, to investigate the molecular dynamics of recently synthesized fast switching ferroelectric side group polymers. The softmode could be studied in detail in the Sc* phase and in the S1* phase. At the transition a pronounced increase of the relaxational strength was found whereas its relaxational frequency remains constant The softmode is the molecular basis for the electroclinic effect which has high application potential for ferroelectric liquid crystal polymers.
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