A methyl free radical source for use in surface studies
作者:
Xiang‐Dong Peng,
Rama Viswanathan,
George H. Smudde,
Peter C. Stair,
期刊:
Review of Scientific Instruments
(AIP Available online 1992)
卷期:
Volume 63,
issue 8
页码: 3930-3935
ISSN:0034-6748
年代: 1992
DOI:10.1063/1.1143240
出版商: AIP
数据来源: AIP
摘要:
A methyl radical source has been developed for use in high vacuum. Methyl radicals are produced through azomethane pyrolysis in a tubular reactor located inside an ultrahigh vacuum chamber. Other gas products include nitrogen from azomethane pyrolysis, and methane, ethane plus hydrogen from the reactions of methyl radicals on the walls of the reactor. Methyl yields as high as 42% have been observed.
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