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Liquid-Liquid Equilibrium of Copolymer Solutions with Broad and Asymmetric Chemical Distributions

 

作者: Margit T. Rätzsch,   Dieter Browarzik,   Horst Kehlen,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1990)
卷期: Volume 27, issue 7  

页码: 809-830

 

ISSN:0022-233X

 

年代: 1990

 

DOI:10.1080/10601329008544807

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A solution of a random copolymer showing polydispersity only with respect to chemical composition is considered. A model distribution very flexible in its breadth and in its asymmetry is used to describe the polydispersity. Based on continuous thermodynamics, equations for the cloud-point curve, the shadow curve, the spinodal, the critical point, and the heterogeneous double critical point are derived. the activity coefficients are calculated with the aid of Huggins' χ-parameter concept assuming χ to depend linearly on the average chemical composition of the copolymer. the influence of the breadth and the asymmetry of the distribution on the liquid-liquid equilibrium of the copolymer solution is discussed.

 

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