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QENS Experiments on a Palladium Containing Organometallic Mesogen

 

作者: R. Bartolino,   G. Coddens,   F. Rustichelli,   M.C. Pagnotta,   C. Versace,   M. Ghedinih,   F. Neve,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  (Taylor Available online 1992)
卷期: Volume 221, issue 1  

页码: 101-108

 

ISSN:1058-725X

 

年代: 1992

 

DOI:10.1080/10587259208037525

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The cyclopalladation reaction of the liquid crystalline species p-dodecyloxy-p'-methylazobenzene (DOMAB) leads to the bimetallic metallo-mesogene [(DOMAB)Pd Cl]2. Both the organic compound and its palladium organometallic complex have been investigated by quasielastic neutron scattering experiments in the nematic and smectic A phases. For DOMAB, the results exhibit a continuous rotation as expected for usual rod-like liquid crystals, while for [(DOMAB)Pd Cl]2they suggest a model wherein only some aliphatic protons can give a rotational diffusion.

 

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