QENS Experiments on a Palladium Containing Organometallic Mesogen
作者:
R. Bartolino,
G. Coddens,
F. Rustichelli,
M.C. Pagnotta,
C. Versace,
M. Ghedinih,
F. Neve,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1992)
卷期:
Volume 221,
issue 1
页码: 101-108
ISSN:1058-725X
年代: 1992
DOI:10.1080/10587259208037525
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The cyclopalladation reaction of the liquid crystalline species p-dodecyloxy-p'-methylazobenzene (DOMAB) leads to the bimetallic metallo-mesogene [(DOMAB)Pd Cl]2. Both the organic compound and its palladium organometallic complex have been investigated by quasielastic neutron scattering experiments in the nematic and smectic A phases. For DOMAB, the results exhibit a continuous rotation as expected for usual rod-like liquid crystals, while for [(DOMAB)Pd Cl]2they suggest a model wherein only some aliphatic protons can give a rotational diffusion.
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