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Determination of cubic‐tetragonal phase boundary in Zr1−XYXO2−X/2solid solutions by Raman spectroscopy

 

作者: Masatomo Yashima,   Katsuya Ohtake,   Haruo Arashi,   Masato Kakihana,   Masahiro Yoshimura,  

 

期刊: Journal of Applied Physics  （AIP Available online 1993）
卷期: Volume 74, issue 12  

页码: 7603-7605

 

ISSN:0021-8979

 

年代: 1993

 

DOI:10.1063/1.354989

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Raman spectroscopy is found to be a powerful tool to determine the structural phase boundary between cubic (Fm3m) and tetragonal (P42/nmc) phase in arc‐melted Zr1−XYXO2−X/2(0.08≤X≤0.24) solid solution. The Raman peak intensity characteristic of the tetragonal phase at about 470 cm−1decreases with the YO1.5contentXand becomes 0 aroundX=0.18.  

 

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