Synthesis and Physicochemical Studies of Chelate Polymers Obtained from the Schiff Base of 5, 5-Methylene-bis-salicylaldehyde with Aniline
作者:
A.M. Karampurwala,
R.P. Patel,
J.R. Shah,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1981)
卷期:
Volume 15,
issue 3
页码: 439-446
ISSN:0022-233X
年代: 1981
DOI:10.1080/00222338108074383
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Cu(II), Ni(II), and Co(II) chelate polymers were prepared from Schiff base of 5, 5′-methylene-bis-salicylaldehyde with aniline. All the polymers are amorphous and insoluble in common organic solvents. They are characterized on the basis of conductivity, infrared, and electronic spectral properties in conjunction with magnetic susceptibility measurements. Various ligand field and nephelauxetic parameters have been evaluated for Ni(II) and Co(II) polychelates. They are consistent with octahedral structure for the former and tetrahedral structure for the latter. Their thermogravimetric analysis show the Co(II) > Ni(II) > Cu(II) order of thermal stability. Kinetic parameters were also obtained.
点击下载:
PDF (331KB)
返 回