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13C NMR Measurement of Hydrogen Bonding Effects for Benzylic Alcohol- Φ Or N Base Complexes : Relationship Between the Oh Stretching Frequencies and the Chemical Shifts of Proton Donor Groups

 

作者: M.C. Moreau Descoings,   F. Halabi,   G. Goethals,   J.P. Séguin,   J.P. Doucet,  

 

期刊: Spectroscopy Letters  （Taylor Available online 1987）
卷期: Volume 20, issue 4  

页码: 351-363

 

ISSN:0038-7010

 

年代: 1987

 

DOI:10.1080/00387018708081556

 

出版商: Taylor & Francis Group

 

关键词: 13C NMR;Hydrogen bond;Benzylic alcohol.

 

数据来源: Taylor

 

摘要:

The carbon shifts induced by hydrogen bonding have been measured for complexes between benzylic alcohol and Φ or n bases (from benzene to collidine) of largely varied strengths. Linear relationships are obtained between corrected induced shifts and the IR frequency shifts ΔνOHbut reverse slopes result for the C-1 and C-α carbons of benzylic alcohol.

 

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