Some relevant parameters on the ‘jacketed’ effect in side-on fixed polysiloxanes
作者:
N. Leroux,
M. Mauzac,
L. Noirez,
F. Hardouin,
期刊:
Liquid Crystals
(Taylor Available online 1994)
卷期:
Volume 16,
issue 3
页码: 421-428
ISSN:0267-8292
年代: 1994
DOI:10.1080/02678299408029167
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
New ‘side-on’ attached liquid crystal polysiloxanes have been synthesized with different fixation ratios of side groups and various degrees of polymerization. For these syntheses, a series of random copoly(hydrogenmethyl-dimethylsiloxane)s, used a precursors, has been realized. Both thermal properties and small angle neutron scattering experiments on these polymers show a dècrease in the nematic ‘jacketed’ effect as the number of mesogenic groups fixed to the backbone decreases and as the main chain length increases.
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