WET PROCESS PHOSPHORIC ACID DEFLUORINATION BY AMINE-BASED EXTRACTANTS
作者:
Aharon Eyal,
Klara Hajdu,
Avraham Baniel,
期刊:
Solvent Extraction and Ion Exchange
(Taylor Available online 1984)
卷期:
Volume 2,
issue 4-5
页码: 659-675
ISSN:0736-6299
年代: 1984
DOI:10.1080/07366298408918469
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Defluorination of WPA to feed grade levels (P:F > 100) was found to be effective with acids of low Al content. Acids with higher Al levels cannot be defluorinated effectively due to a sharp decrease in the distribution coefficient of the fluorine. This is attributable to complexation of fluorine by Al. An important part of manufactured phosphoric acids contain aluminum in levels that render defluorination to feed grade requirements impractical. Treating such acids with SiO2as well as preconcentration prior to extraction result in some improvement in extractability but provides for marginal improvements only.
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