首页   按字顺浏览 期刊浏览 卷期浏览 Eine Neue Einfache Synthese von L-Vinelose
Eine Neue Einfache Synthese von L-Vinelose

 

作者: Almuth Klemer,   Helmut Stegt,  

 

期刊: Journal of Carbohydrate Chemistry  （Taylor Available online 1985）
卷期: Volume 4, issue 2  

页码: 205-213

 

ISSN:0732-8303

 

年代: 1985

 

DOI:10.1080/07328308508058832

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Reduction of methyl 6-deoxy-2,3-0-isopropylidene-3-C-methyl-α-L-lyxo-hexopyranosid-4-ulose (2) with sodium tetrahydroborate or L-selectride produces exclusively the L-talo-configurated 4-hydroxy compound (3), which is transformed to methyl 6-deoxy-3,4-O-isopropylidene-3-C-methyl-α-L-talopyranoside (4). Methylation of the 2-hydroxy group and hydrolysis yields L-vinelose (6) .

 

点击下载:  PDF (296KB)



返 回