Extraction of Sc, Mn(II), Co, Ni, Cu, Zn, Ga, Zr, Nb, Mo, Pd, Ag, Cd, In, Sb(III), Te(IV), Ta, W. Pt, Au, Hg, TI(III), Pb, Bi, Th and U from hydrochloric acid solutions by a number of phosphoryl-containing azapodands with an o-phenylene fragment located between the phosphoryl group and the polyester chain has been investigated. The influence of the reagent structure, the nature of an organic solvent, and the compositions of the organic and aqueous phases on the process of extraction is considered.