Evidence from circular dichroism for the binding of hydrogen ions and calcium ions by poly(L‐proline)
作者:
Jung‐Teh Lo,
Wayne L. Mattice,
期刊:
Biopolymers
(WILEY Available online 1976)
卷期:
Volume 15,
issue 1
页码: 15-19
ISSN:0006-3525
年代: 1976
DOI:10.1002/bip.1976.360150103
出版商: Wiley Subscription Services, Inc., A Wiley Company
数据来源: WILEY
摘要:
AbstractThe positive circular dichroism band observed near 228 nm with poly(L‐proline) responds in a similar fashion to HCl and CaCl2. The spectra in the HCl solutions are compatible with a simple binding equation and a pKnear −2 for the dissociation of a proton from a protonated peptide bond in poly(L‐proline). The data obtained in CaCl2is susceptible to the same analysis, suggesting a pKnear −1.5 for the dissociation of a calcium ion from its complex with poly(L
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