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Analysis of Liquid-Vapour Phase Transitions for Restricted Primitive Model of Ionic System in Mean Spherical Approximation

 

作者: N.C. Tkachev,  

 

期刊: Physics and Chemistry of Liquids  (Taylor Available online 1996)
卷期: Volume 31, issue 2  

页码: 71-81

 

ISSN:0031-9104

 

年代: 1996

 

DOI:10.1080/00319109608029560

 

出版商: Taylor & Francis Group

 

关键词: Restricted primitive model;mean spherical approximation;equation of state;evaporation;critical behaviour

 

数据来源: Taylor

 

摘要:

Within the framework of MSA exact solution for charged hard spheres with equal diameters found by Waisman and Lebowitz for Coulomb part of free energy and Mansooriet al., approximation for hard sphere contribution characteristics of evaporation phase transitions in terms of the equation of state have been estimated. The phase diagram has been evaluated and the behaviour of thermodynamic properties studied in a wide range of temperature and pressure for the example close to KF system. The position of the critical point is in accordance with the earlier determination of Telo da Gama, Evans and Sluckin using generalised MSA. Numerical values of the coefficients in the expansion of the relative deviation in pressure in powers of temperature and order parameter have been simply estimated near the critical region. Temperature and pressure dependencies of entropy and isothermal compressibility are typical enough for fluid systems, notwithstanding the collective nature of ionic interactions. In addition, the known Kauzman entropy paradox arises at low temperatures.

 

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