TKIE ENTROPIC SPRING IN RUBBER ELASTICITY
作者:
J. H. Weiner,
J. Gao,
期刊:
Journal of Thermal Stresses
(Taylor Available online 1992)
卷期:
Volume 15,
issue 2
页码: 329-329
ISSN:0149-5739
年代: 1992
DOI:10.1080/01495739208946140
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The concept of a long-chain molecule acting as a spring in tension with the restoring force based on changes in entropy rather than energy has played a central role in the molecular theory of rubber elasticity since its inception over 50 years ago [1, 2], It is here reviewed and discussed from several different viewpoints based, in part, on insights gained from the computer simulation of atomistic models. Included are (a) kinetic interpretation of the force [3], (b) the role of excluded volume interactions in dense polymer systems [4], and (c) the extent of the utility of the entropic spring concept in nonequilib-rium situations [5].
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