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Application of Ion-Selective Electrodes as Reference Electrodes

 

作者: Ivan Sekerka,   JosefF. Lechner,  

 

期刊: Analytical Letters  (Taylor Available online 1979)
卷期: Volume 12, issue 12  

页码: 1239-1248

 

ISSN:0003-2719

 

年代: 1979

 

DOI:10.1080/00032717908067914

 

出版商: Taylor & Francis Group

 

关键词: Reference Electrodes;Ion-Selective Electrodes;Interference;Low Levels of Halides;Silver;Mercury;Construction;Performance

 

数据来源: Taylor

 

摘要:

Reference electrodes limiting interfering effects of conventional reference electrodes on the measurement involving ion-selective electrodes have been developed. They are constructed of a plastic body with porous plug or sleeve junction. Solid state, low impedance, ion-selective electrodes (cupric, cadmium, fluoride) in the equilibrium of corresponding ion solution are used as the half-cells. The absence of interfering ions in the electrolyte allows the determination of the ion of interest at extremely low levels without interference. The electrodes have good reproducibility and stable intercomparison potentials of ± 0.2 mV. The performance of the electrodes has been tested for the measurement of sub-ppm halide levels. Data on stability, reproducibility, effects of temperature, ionic strengthand pH is presented and compared to that of conventional reference electrodes.

 

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