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ChemInform Abstract: Chemical and Electrochemical Oxidation of CpRe(PAr3)2H2 Complexes to Give Stable 17‐Electron Radical Cations. Disproportionation to Diamagnetic Species via Electron‐Transfer Catalysis.

 

作者: M. R. DETTY,   W. D. JONES,  

 

期刊: ChemInform  (WILEY Available online 2016)
卷期: Volume 19, issue 1  

页码: -

 

ISSN:0931-7597

 

年代: 2016

 

DOI:10.1002/chin.198801296

 

出版商: WILEY‐VCH Verlag GmbH

 

数据来源: WILEY

 

摘要:

AbstractElectrochemical oxidations of (I) in both MeCN and CH2Cl2give stable 17‐electron radical monocations as determined by controlled‐potential thin‐layer coulometry and double‐potential step chronocoulometry.

 

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