Effect of pressure on thermal order parameter fluctuations and phase boundaries in polymer blends and diblock copolymers
作者:
D. Schwahn,
H. Frielinghaus,
K. Mortensen,
K. Almdal,
T. Springer,
期刊:
Neutron News
(Taylor Available online 1997)
卷期:
Volume 8,
issue 1
页码: 32-34
ISSN:1044-8632
年代: 1997
DOI:10.1080/10448639708231962
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The order parameter in binary homopolymer blends or diblock copolymers describes the deviations of the local composition of both components from the mean value. The Fourier transform of the fluctuation spectrum yields the structure factor S(Q), where Q is the wave number of the fluctuations or the momentum transfer in scattering. S(Q→O) is the susceptibility related to the second derivative of the Gibbs potential of mixing with respect to the composition, t32AG/t32z [1–3]. Binary polymer blends normally reveal a miscibility gap that separates the homogeneous one-phase from the two-phase region where precipitation appears. Approaching the critical temperature Tc, the strength and range of thermal fluctuations of the order parameter increase and diverge if Tcis approached.
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