Normal stress differences in liquid crystalline hydroxypropylcellulose solutions
作者:
S.‐G. Baek,
J. J. Magda,
S. Cementwala,
期刊:
Journal of Rheology
(AIP Available online 1993)
卷期:
Volume 37,
issue 5
页码: 935-945
ISSN:0148-6055
年代: 1993
DOI:10.1122/1.550404
出版商: The Society of Rheology
关键词: Normal stresses;Hydroxypropyl cellulose, rheology of;Lyotropic polymers, rheology of;Viscosity;Liquid crystals, rheology of;SOLUTIONS;LIQUID CRYSTALS;LYOTROPIC CRYSTALS;CELLULOSE;CRESOLS;VISCOSITY;STRESSES;SHEAR PROPERTIES
数据来源: AIP
摘要:
All three viscometric functions are investigated as a function of shear rate for lyotropic solutions of hydroxypropyl cellulose (HPC). Through the use of m‐cresol as the solvent, it was possible to investigate liquid crystal solutions at lower polymer volume fractions than have previously been studied for HPC. We find no evidence of a three‐region viscosity curve, as has been widely reported for HPC at higher polymer volume fractions. The first and second normal stress differences (N1andN2, respectively) both change sign twice as the shear rate is varied.
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