Anomalous point defect formation and phase transitions: The significance of a cube root law
作者:
N. Hainovskyand,
J. Maier,
期刊:
Radiation Effects and Defects in Solids
(Taylor Available online 1995)
卷期:
Volume 137,
issue 1-4
页码: 267-271
ISSN:1042-0150
年代: 1995
DOI:10.1080/10420159508222733
出版商: Taylor & Francis Group
关键词: defect-defect interaction;phase transition;thermodynamics;ionic conductivity
数据来源: Taylor
摘要:
Here we discuss a phenomenological approach for the understanding of the anomalous point defect formation in ionic crystals prior to the phase transition as well as the prediction of the phase transition temperatures. Quantitative agreement was achieved using a simple cube root law for the defect-defect interaction potential. This approach was applied to materials (AgCl, AgBr, AgI, PbF2) with different structures (rock salt, fluorite, wurtzite), different types of disorder (Frenkel and anti-Frenkel) and different types of phase transition (solid-liquid and solid-solid, first and second order). The computed defect-defect interaction leads to a quantitative description of the conductivity anomalies and to the prediction of a phase instability at a temperature which is very close to the actual transition point.
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