Primary chemical events in ion bombarded polystyrene films: An infrared study
作者:
O. Puglisi,
A. Licciardello,
S. Pignataro,
L. Calcagno,
G. Foti,
期刊:
Radiation Effects
(Taylor Available online 1986)
卷期:
Volume 98,
issue 1-4
页码: 161-170
ISSN:0033-7579
年代: 1986
DOI:10.1080/00337578608206108
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The chemical phenomenology which occurs in polystyrene films bombarded with low doses 100 keV He+ions has been investigated by infrared spectroscopy. The results obtained show that the polymer is rapidly transformed into a different chemical compound consistent with high cross-linking as indicated by low solubility in CHCI3. The I.R. finding is in agreement with XPS findings and indicates that the observed phenomenology occurs via a mechanism which eliminates the electronic “π” system of the phenyl ring and gives rise to alkene-type bonding.
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