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About Intermolecular Interaction, Submolecular Structure, and Paramagnetism of Polyconjugated Systems

 

作者: A.A. Berlin,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  （Taylor Available online 1971）
卷期: Volume 5, issue 7  

页码: 1187-1203

 

ISSN:0022-233X

 

年代: 1971

 

DOI:10.1080/00222337108061099

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

It is shown that macromolecules with polyconjugated systems are capable of forming strong 7r-complex associates. The paramagnetic centers cause intercombinative transitions in auto- or α-complexes with other molecules and increase their reactivity (“effect of local activation”).

 

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