RADIATION CHEMISTRY OF CYCLOHEXANE: III. EFFECT OF BENZENE AND IODINE ON THE ISOTOPIC COMPOSITION OF RADIOLYTIC HYDROGEN FROM C6D12–C6H12MIXTURES
作者:
P. J. Dyne,
W. M. Jenkinson,
期刊:
Canadian Journal of Chemistry
(NRC Available online 1961)
卷期:
Volume 39,
issue 11
页码: 2163-2170
ISSN:0008-4042
年代: 1961
DOI:10.1139/v61-288
出版商: NRC Research Press
数据来源: NRC
摘要:
The isotopic composition of hydrogen evolved in the radiolysis of C6D12–C6H12mixtures has been measured in the presence of various amounts of benzene and iodine. The yield of the unimolecular decomposition and the specific yield of the bimolecular reaction are reduced in approximately the same proportion as the yield of total hydrogen. It is concluded that (i) iodine and benzene interact to a comparable extent with both unimolecular and bimolecular decomposition modes, (ii) it is probable that neither of these additives act by scavenging, and (iii) it is probable that they act by quenching a common precursor of the two decomposition modes.
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