Polymers as Structured Continua
作者:
C. C. Ling,
S. J. Allen,
K. A. Kline,
期刊:
Transactions of the Society of Rheology
(AIP Available online 1972)
卷期:
Volume 16,
issue 1
页码: 129-145
ISSN:0148-6055
年代: 1972
DOI:10.1122/1.549249
出版商: The Society of Rheology
数据来源: AIP
摘要:
The ability of microstructure theory to predict the behavior of polymers in transient shear fields is examined. Apparent viscosity and normal stress differences are formed for the cases of shear relaxation and growth using a microstructure model. The results agree qualitatively with experimental results for three different viscoelastic solutions. The analytical results are also compared to those of the Spriggs 4‐constant model and found to be in exact agreement for low shear rates. This agreement permits determination of the phenomenological coefficients in terms of the Spriggs constants.
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