Do alkoxy chains behave like a solvent in the D phase? DSC study of binary systems, ANBC (nC) (nC = 8, 16 and 18)-n-tetradecane
作者:
KAZUYA SAITO,
AYAKO SATO,
MICHIO SORAI,
期刊:
Liquid Crystals
(Taylor Available online 1998)
卷期:
Volume 25,
issue 4
页码: 525-530
ISSN:0267-8292
年代: 1998
DOI:10.1080/026782998206047
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The phase behaviour of the binary systems ANBC(nC)-n-tetradecane, for nC = 8, 16 and 18, was examined using DSC, paying special attention to the role of the alkoxy chain of the ANBC molecule in the D phase. The dependence of the SmC-D and D-isotropic liquid transition temperatures upon the apparent average number of paraffinic carbon atoms closely resembles the nC dependence in the series of neat ANBCs, demonstrating that the alkoxy chain behaves, at least in part, like the solvent in lyotropic liquid crystals. The D phase was not detected in ANBC(8)-n-tetradecane.
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