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A Nmr Study Of Barriers To Internal Rotation In 3-Diazo-2-butanone

 

作者: R. Curci,   F. Difuria,   V. Lucchini,  

 

期刊: Spectroscopy Letters  (Taylor Available online 1974)
卷期: Volume 7, issue 4-5  

页码: 211-218

 

ISSN:0038-7010

 

年代: 1974

 

DOI:10.1080/00387017408067238

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

It is recognized that in α-diazoketones free rotation about the central C-C bond might be hindered through positive overlap of the carbonyl π-system with the p orbital on the α-carbon part of the CNN fragment.1,2

 

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