A Nmr Study Of Barriers To Internal Rotation In 3-Diazo-2-butanone
作者:
R. Curci,
F. Difuria,
V. Lucchini,
期刊:
Spectroscopy Letters
(Taylor Available online 1974)
卷期:
Volume 7,
issue 4-5
页码: 211-218
ISSN:0038-7010
年代: 1974
DOI:10.1080/00387017408067238
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
It is recognized that in α-diazoketones free rotation about the central C-C bond might be hindered through positive overlap of the carbonyl π-system with the p orbital on the α-carbon part of the CNN fragment.1,2
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