Why Mono- or Poly-Layered Intercalated Sheets in Graphite-Electron Donors Systems?
作者:
Phillipe Lagrange,
Albert Herold,
Claire Herold,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1998)
卷期:
Volume 310,
issue 1
页码: 33-41
ISSN:1058-725X
年代: 1998
DOI:10.1080/10587259808045311
出版商: Taylor & Francis Group
关键词: graphite;intercalated sheets;electron donors;crystal structure
数据来源: Taylor
摘要:
Intercalation into graphite of electron donors is discussed, regarding the nature of the chemical species to be intercalated. In the binary compounds, the intercalated sheets are always mono-layered, while, in the ternaries, they are poly-layered, as soon as the electronegativities of both intercalated elements exhibit a sizeable difference. In the case of the ternary compounds, the intercalated sheets can be regarded as 2D slices of the corresponding bulk binary compounds. These slices are subjected to various distortions, that are caused by the presence of the adjacent graphene planes
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