N-Substituted Aldonamides V X-Ray Diffraction Study of the Crystal and Thermotropic and Lyotropic Mesophases of N-Alkylribonamides
作者:
Bernard Gallot,
Manon Loos,
Daniélle Baeyens-volant,
Christiane David,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1992)
卷期:
Volume 210,
issue 1
页码: 143-153
ISSN:1058-725X
年代: 1992
DOI:10.1080/10587259208030762
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The structure of two N-alkylribonamides both in the anhydrous state and in concentrated water solution has been studied by X-ray diffraction. A Lamellar Crystalline, a Lamellar Liquid-Crystalline and a Cylindrical Hexagonal Liquid-Crystalline Structures have been found. The influence of temperature and of water concentration on the geometrical parameters of the mesophases has been established. The organization of the molecules in the three structures is described and a step by step melting behavior is proposed for the N-alkylaldonamides.
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