Intramolecular Charge Transfer Complexes. 4. Poly(N-(2-hydroxyethyl)carbazolyl Acrylate-co-Picryl Methacrylate)
作者:
V. Percec,
A. Natansohn,
C.I. Simionescu,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1981)
卷期:
Volume 15,
issue 3
页码: 405-415
ISSN:0022-233X
年代: 1981
DOI:10.1080/00222338108074380
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Radical copolymerization of N-(2-hydroxyethyl)carbazolyl acry-late with picryl methacrylate takes place mainly through the inter-monomeric charge transfer complex (CTC) in dioxane solution. When the solvent is 1, 2-dichloroethane, concurrent chain transfer reactions arise. The copolymers obtained are intramolecular CTC. The charge transfer interaction depends on copolymer composition and conformation, and on the copolymerization solvent.
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