Splay elasticity in an oligomeric liquid crystal
作者:
GregoryA. Dilisi,
Charles Rosenblatt,
AnselmC. Griffin,
Uma Hari,
期刊:
Liquid Crystals
(Taylor Available online 1990)
卷期:
Volume 8,
issue 3
页码: 437-443
ISSN:0267-8292
年代: 1990
DOI:10.1080/02678299008047359
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A magnetically-induced Freedericksz transition was used in conjunction with capacitance techniques to determine the splay elastic constant of the 4,4′-dialkoxyphenylbenzoate monomer ‘5OO5rsquo; [C5H11OC6H4COOC6H4OC5H11] and its dimer. As a function of reduced temperature in the nematic phase, it was found thatK11of the dimer is only about 20 per cent larger than that of the monomer. Moreover, the values ofK11/S2versus reduced temperature, whereSis the scalar order parameter, are equal to within experimental noise. These results suggest that for short oligomers Meyer's entropic model for splay elasticity in polymer liquid crystals is not applicable. A lowest order correction to the entropic model is suggested, which partially accounts for excluded volume and dispersive effects.
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