首页   按字顺浏览 期刊浏览 卷期浏览 Splay elasticity in an oligomeric liquid crystal
Splay elasticity in an oligomeric liquid crystal

 

作者: GregoryA. Dilisi,   Charles Rosenblatt,   AnselmC. Griffin,   Uma Hari,  

 

期刊: Liquid Crystals  (Taylor Available online 1990)
卷期: Volume 8, issue 3  

页码: 437-443

 

ISSN:0267-8292

 

年代: 1990

 

DOI:10.1080/02678299008047359

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A magnetically-induced Freedericksz transition was used in conjunction with capacitance techniques to determine the splay elastic constant of the 4,4′-dialkoxyphenylbenzoate monomer ‘5OO5rsquo; [C5H11OC6H4COOC6H4OC5H11] and its dimer. As a function of reduced temperature in the nematic phase, it was found thatK11of the dimer is only about 20 per cent larger than that of the monomer. Moreover, the values ofK11/S2versus reduced temperature, whereSis the scalar order parameter, are equal to within experimental noise. These results suggest that for short oligomers Meyer's entropic model for splay elasticity in polymer liquid crystals is not applicable. A lowest order correction to the entropic model is suggested, which partially accounts for excluded volume and dispersive effects.

 

点击下载:  PDF (374KB)



返 回