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Thermodynamics of polystyrene solutions. II. Glass contributions and thermal behavior

 

作者: SamuelH. Maron,   CharlesA. Daniels,  

 

期刊: Journal of Macromolecular Science, Part B  (Taylor Available online 1968)
卷期: Volume 2, issue 4  

页码: 769-780

 

ISSN:0022-2348

 

年代: 1968

 

DOI:10.1080/00222346808212468

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The Maron theory has been used to deduce from available thermal and other data expressions for the heats of solution and dilution of polystyrene in nine solvents. Also, a direct method is described by means of which the energy of the glass can be determined from heat of solution measurements. Applied to solutions of polystyrene in toluene, ethyl benzene, and chlorobenzene, this method gives for the energy frozen in the glass 8.02 0.19 cal/g of sample for a polymer of M2 = 150,000. This value compares reasonably well with the value of 7.07 cal/g obtained by Bianchi for a polymer of M2 = 250,000.

 

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