Thermopower of Sr1−xLaxTiO3ceramics
作者:
Ralf Moos,
Alain Gnudi,
Karl Heinz Ha¨rdtl,
期刊:
Journal of Applied Physics
(AIP Available online 1995)
卷期:
Volume 78,
issue 8
页码: 5042-5047
ISSN:0021-8979
年代: 1995
DOI:10.1063/1.359731
出版商: AIP
数据来源: AIP
摘要:
The thermopower &eegr; of Sr1−xLaxTiO3ceramics was investigated up tox=0.5 and in the temperature range between 150 K and 1200 K. In addition, the carrier concentrationnwas determined by Hall measurements and by a chemical Ti3+‐analysis. For low temperatures and highn, &eegr; depends linearly on temperature and onn−2/3, as expected from a degenerate quasi free electron gas. In the case of high temperatures and lown, the absolute value of &eegr; rises with 1.5⋅ln10⋅k/eper decade of temperature and with ln10⋅k/eper decade of carrier concentration, as expected from a classical broad‐band semiconductor obeying the Boltzmann statistics. In the range of degeneration an effective massmeffof 4.2 electron masses can be deduced without the assumption of a transport factorAe. In the classical rangeAe=3 can be evaluated, requiring only a temperature and lanthanum independentmeff. Thus, the thermopower of Sr1−xLaxTiO3ceramics can be described by a constant effective mass and a constant transport factor within a wide range of temperature and lanthanum content. Furthermore, the transition from degeneration to classical behavior can be described as a function of temperature and electron density, e.g., at room temperature it takes place at aboutx≊0.2 (i.e.,n≊3.4⋅1021/cm3). ©1995 American Institute of Physics.
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