Measurement and application of limiting activity coefficients
作者:
C. A. Eckert,
B. A. Newman,
G. L. Nicolaides,
T. C. Long,
期刊:
AIChE Journal
(WILEY Available online 1981)
卷期:
Volume 27,
issue 1
页码: 33-40
ISSN:0001-1541
年代: 1981
DOI:10.1002/aic.690270107
出版商: American Institute of Chemical Engineers
数据来源: WILEY
摘要:
AbstractInfinite dilution activity coefficients (γ∞) in binary liquid mixtures are data of wide practical and theoretical applicability, but their extensive use has been hindered by the experimental limitations of classical vapor‐liquid equilibrium techniques. Two new experimental methods for accurate γ∞determinations are presented. These techniques, both faster and more accurate than classical methods, are complementary, and their applicability to different types of binary systems is di
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