Study of tensile deformation in shockedZ‐cut, &agr;‐quartz using time resolved Raman spectroscopy
作者:
S. M. Gallivan,
Y. M. Gupta,
期刊:
Journal of Applied Physics
(AIP Available online 1995)
卷期:
Volume 78,
issue 3
页码: 1557-1564
ISSN:0021-8979
年代: 1995
DOI:10.1063/1.360249
出版商: AIP
数据来源: AIP
摘要:
An experimental method has been developed to use time resolved Raman spectroscopy as a microscopic probe of tensile deformation in shocked crystals. Tension is produced in the sample interior by the interaction of rarefaction waves generated in plate impact, uniaxial strain experiments. Optical fibers are used to transmit visible light from a pulsed laser to the sample and to transmit the scattered light to a recording system with 50 ns time resolution. The strain‐induced shift of the 464 cm1,A1line of &agr;‐quartz was measured. Results are presented for longitudinal stresses ranging from 54 kbar in tension to 60 kbar in compression. For each experiment, the 464 cm−1line exhibited a shift toward higher frequency in compression, followed by a return to the ambient position upon unloading, followed by a comparable shift toward lower frequency in tension. This latter shift correlates to a marked increase in the intertetrahedral (Si–O–Si) bond angle of quartz with tension. Comparison with earlier work and the analysis presented here suggests that there is also significant distortion of the SiO4tetrahedra and a mechanism for this distortion is proposed. ©1995 American Institute of Physics.
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