Oscillatory continuum fluorescence from high vibrational levels of theE(0+) ion-pair state of IBr
作者:
K.P. Lawley,
D. Austin,
J. Tellinghuisen,
R.J. Donovan,
期刊:
Molecular Physics
(Taylor Available online 1987)
卷期:
Volume 62,
issue 5
页码: 1195-1205
ISSN:0026-8976
年代: 1987
DOI:10.1080/00268978700102901
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
An analysis of the structured continuum fluorescence (280–390 nm), arising from excitation of IBr at 180 nm, 193 nm and 200 nm, is reported. The fluorescence originates from high vibrational levels of theE(0+) state (v′ ≈ 110–205) and terminates in the continuum of the ground electronic state. TheEstate is quite tightly constrained in the region 3.1–4.8 Å by the Rittner potential and known RKR points, but detailed fitting of the interference structure provides additional information about the ground state beyond 2.9 Å. The transition dipole moment appears to pass through a broad maximum in thisRrange.
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