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Peroxo Salts as Initiators of Vinyl Polymerization. 6. Kinetics of Polymerization of Acrylonitrile Initiated by Potassium Peroxodisulfate in Aqueous Medium-Ag+Catalysis

 

作者: S.P. Manickam,   N.R. Subbaratnam,   K. Venkatarao,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  （Taylor Available online 1981）
卷期: Volume 15, issue 8  

页码: 1511-1519

 

ISSN:0022-233X

 

年代: 1981

 

DOI:10.1080/00222338108056798

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The kinetics of polymerization of acrylonitrile initiated by potassium peroxodisulfate in neutral and acid conditions was studied. Rpdepended upon [S2O82-]1/2and [monomer]3/2both in neutral and acid solutions. The influence of ionic strength and the cata-lytic effect of Ag+on the System are discussed. Suitable mech-anisms are proposed.

 

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