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Growth Mechanism and Twinning of Sucrose Effected by Surface Adsorption Processes

 

作者: B. Döhl,   H. Follner,  

 

期刊: Crystal Research and Technology  (WILEY Available online 1992)
卷期: Volume 27, issue 1  

页码: 3-12

 

ISSN:0232-1300

 

年代: 1992

 

DOI:10.1002/crat.2170270102

 

出版商: WILEY‐VCH Verlag

 

数据来源: WILEY

 

摘要:

AbstractGrowth experiments with sucrose dependent on temperature and supersaturation of solutions were carried out to find the conditions for appearance of the three different growth types. Measurements of growth rates of {110} and {110} faces at 50°C and supersaturationcs= 10% resulted in the known feature that in pure solutions a crystal grows faster in positiveb‐direction than in the negative one. Addition of raffinose stopped growth of {110}. In an electric field generated by 20 kV direct voltage (crystal orientation: negative pole ofb‐axis pointed towards the negative electric pole) the crystal grew in negativeb‐direction three times faster than in the positive one. In the presence of raffinose the growth rates in both directions become equal. If the crystal is turned by 180° in the solution (pure solution and in the presence of raffinose) the growth behaviour is the same as without an electric field. These results can be interpreted in such way that in pure solutions sucrose molecules adsorb to {110} (bonds exist between the fructose rings of molecules in liquid and solid phases) and that in presence of raffinose these molecules adsorb to {110} (bonds exist between glucose (solid) and galactose rings (liquid phases)). By the electric field the adsorption is hindered. The theory is in accordance with the fact that crystals situated in a suspension of the solution can intergrow with a host crystal in twin positions (in pure solutions on {110} and in the presence of raffinose on

 

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