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Enclosed flow tube injector system for low temperature kinetic studies

 

作者: Bruce Henry,   Alan Fried,   Jack Fox,   Jack G. Calvert,   Michael Mozurkewich,  

 

期刊: Review of Scientific Instruments  (AIP Available online 1994)
卷期: Volume 65, issue 5  

页码: 1675-1678

 

ISSN:0034-6748

 

年代: 1994

 

DOI:10.1063/1.1144858

 

出版商: AIP

 

数据来源: AIP

 

摘要:

A new enclosed injector system for low temperature kinetic studies is described. This system offers a number of advantages over more conventional designs of moveable inlet injectors. The enclosed injector prevents the introduction of contaminants into the flow reactor. In conventional designs, ambient contaminants adsorbed onto the outside of the injector could be transported into the flow reactor. The enclosed injector exposes the reactant gas to the same length of inlet tubing at a uniform temperature regardless of the injector position. In addition, the enclosed injector minimizes temperature gradients in the flow reactor caused by heat transfer along the injector. This is a particular problem when the flow reactor is operated near atmospheric pressure at reduced temperatures. Finally, this design is significantly more compact than conventional injector designs. This system has been successfully employed in studies of the heterogeneous reaction of N2O5with sulfuric acid aerosols over the temperature range 225–293 K.  

 

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