STRUCTURE AND PROPERTIES OF CYCLIC COMPOUNDS: XI. DISSOCIATION CONSTANTS OF THE CYANOHYDRINS OF SOME METHYLCYCLOHEXANONES
作者:
Owen H. Wheeler,
Jacob Z. Zabicky,
期刊:
Canadian Journal of Chemistry
(NRC Available online 1958)
卷期:
Volume 36,
issue 4
页码: 656-660
ISSN:0008-4042
年代: 1958
DOI:10.1139/v58-091
出版商: NRC Research Press
数据来源: NRC
摘要:
The dissociation constants of the cyanohydrins of a series of methylcyclohexanones have been measured. The polymethylcyclohexanone cyanohydrins show increasing instability on substitution owing to the effects of "axial crowding". The cyanohydrins of 3- and 4-methylcyclohexanone were found to be more stable than that of cyclohexanone and to explain this a new concept of "equatorial interference" is introduced.
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