Spectroscopy of chromium compounds in molten salts
作者:
H. C. Brookes,
S. N. Flengas,
期刊:
Canadian Journal of Chemistry
(NRC Available online 1970)
卷期:
Volume 48,
issue 1
页码: 55-58
ISSN:0008-4042
年代: 1970
DOI:10.1139/v70-008
出版商: NRC Research Press
数据来源: NRC
摘要:
Modifications to the Hitachi Perkin–Elmer 139 ultraviolet–visible spectrophotometer are described which enable absorption spectra of molten salts to be measured to 865 °C. The instrument can be readily reconverted for ambient temperature measurements. The solubilities and the limiting heats of solution of Ag2CrO4and PbCrO4in equimolar NaNO3–KNO3have been measured spectrophotometrically from 250 to 350 °C. The absorption spectrum of dilute solutions of Cr(III) in CsCl has been measured, the octahedral CrCl63−being present in solution at 700 °C.
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