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Electrical conductivity of chelate polymers. II

 

作者: M.S. Patel,  

 

期刊: Journal of Macromolecular Science, Part B  (Taylor Available online 1987)
卷期: Volume 26, issue 1  

页码: 97-104

 

ISSN:0022-2348

 

年代: 1987

 

DOI:10.1080/00222348708248060

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The electrical conductivity of coordinated polychelates derived from bissemicarbazone and bisthiosemicarbazone of 5. 5′-methylene-bis-salicylaldehyde with Cu(II), Co(II), Ni(II), and Mn(II) metal ions was measured at various temperatures. The results for polychelates of both ligands showed that the conductivity varied as Cu(Il) > Ni(II) > Co(II) > Mn(II) polychelate, and that the activation energy, E, increased from Cu(II) through Ni(II) and Mn(II) to Co(II) polychelates. Hall effect and Seebeck effect studies of Cu(II) polychelates revealed that they are found as p-type semiconductors and that the mechanism of transport is of the hopping type.

 

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