首页   按字顺浏览 期刊浏览 卷期浏览 Standard Chemical Thermodynamic Properties of Polycyclic Aromatic Hydrocarbons and Thei...
Standard Chemical Thermodynamic Properties of Polycyclic Aromatic Hydrocarbons and Their Isomer Groups. II. Pyrene Series, Naphthopyrene Series, and Coronene Series

 

作者: Robert A. Alberty,   Michael B. Chung,   Andrea K. Reif,  

 

期刊: Journal of Physical & Chemical Reference Data  (AIP Available online 1989)
卷期: Volume 18, issue 1  

页码: 77-109

 

ISSN:0047-2689

 

年代: 1989

 

DOI:10.1063/1.555826

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The tables in our first paper on polycyclic aromatic hydrocarbons [J. Phys. Chem. Ref. Data17, 241 (1988)] have been extended by calculating thermodynamic properties for the first four isomer groups in the pyrene series, the first three isomer groups in the naphthopyrene series, and the first three isomer groups in the coronene series. Successive isomer groups in each series differ by C4H2. Since chemical thermodynamic properties are known for only a limited number of polycyclic aromatic hydrocarbons, the properties of individual species have been estimated using Benson group values of Stein and Fahr for temperatures from 298.15 to 3000 K. Values ofC○P,S°, &Dgr;fH°, and &Dgr;fG° have been calculated in joules for a standard state pressure of 1 bar. The chemical thermodynamic properties of the individual species have also been calculated. The isomer group values provide a basis for extrapolating to higher carbon numbers where it is not feasible to consider individual molecular species.

 

点击下载:  PDF (2428KB)



返 回