Pyrones et Pyronones. IISynthèse d'alcoyl‐6 pyrones‐2 par réduction d'alcoyl‐6 pyronones
作者:
M. J. D. van Dam,
F. Kögl,
期刊:
Recueil des Travaux Chimiques des Pays‐Bas
(WILEY Available online 1964)
卷期:
Volume 83,
issue 1
页码: 39-49
ISSN:0165-0513
年代: 1964
DOI:10.1002/recl.19640830105
出版商: WILEY‐VCH Verlag
数据来源: WILEY
摘要:
By reaction of triacetic lactone with phosphoryl chloride 4‐chloro‐6‐methyl‐2‐pyrone was prepared; this happened to be identical with a compound of uncertain structure, previously obtained from acetyl chloride and 1,1‐dichloroethene. Reductive dechlorination yielded 6‐methyl‐2‐pyrone.Both 6‐cyclopentyl‐3‐cyclopentylcarbonyl‐4‐hydroxy‐2‐pyrone and 6‐cyclopentyl‐4‐hydroxy‐2‐pyrone were prepared by conventional methods; they have bacteriostatic properties. By chlorination and reduction of the latter compound 6‐cyclopentyl‐2‐pyrone was obtained.The mechani
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