Reversible solvent swelling in pigment gallstones
作者:
JudithM. Conway-Ayoub,
J. Donald Ostrow,
StephenH. Carr,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1988)
卷期:
Volume 27,
issue 2-3
页码: 145-150
ISSN:0022-2348
年代: 1988
DOI:10.1080/00222348808245760
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The reversibility of solvent swelling and the existence of an equilibrium swelling ratio, qeq, has been established for pigment gallstone particles. A simple technique was devised to demonstrate that solvent imbibition in pigment gallstone particles is reversible. This finding confirms unequivocally that the molecular makeup of pigment gallstones involves polymer networks. In addition, this new method permits serial direct observation of the interactions between pigment gallstone particles and the solvent. Application of the technique to other network polymers should be readily possible.
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