An Empirical Constitutive Model for Polymer Solutions
作者:
Glen Pearson,
Stanley Middleman,
期刊:
Transactions of the Society of Rheology
(AIP Available online 1976)
卷期:
Volume 20,
issue 4
页码: 559-573
ISSN:0148-6055
年代: 1976
DOI:10.1122/1.549425
出版商: The Society of Rheology
数据来源: AIP
摘要:
Constitutive relations generally require a large set of fluid relaxation times to provide an accurate fluid description. In situations involving the solution of the dynamic equations of flow simultaneously with the constitutive relation, the use of a single relaxation time model is desirable because of the time consuming nature of the numerical solution schemes. This work presents a single relaxation time fluid model, obtained by empirically modifying the existing form of the Meister model. The empiricisms take the form of two functions of deformation rate, chosen so the model will predict quantitatively the time to maximum overshoot and the magnitude of the maximum overshoot in transient shear stress for a “start‐up” experiment. The modified model compares very well to transient and steady data for five polymer solutions and to the predictions of the Carreau Model B.
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