Visual observations of slip in flow of polymer melts
作者:
G. Mennig,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1977)
卷期:
Volume 14,
issue 2
页码: 231-240
ISSN:0022-2348
年代: 1977
DOI:10.1080/00222347708220366
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The behavior of polymer melts in the presence of solid walls has been studied by recording the displacement of differently colored melts of the same stock in a capillary rheometer before and after flow. For emulsion PVC (E-PVC) without lubricant and plasticizer it was found that at T = 443°K there is almost complete slip at the wall (metal). Slip of both E-PVC and suspension PVC (S-PVC) gradually decreases with increasing temperature. Since this is a reversible phenomenon it cannot be directly related to the particle structure, which disappears irreversibly with increasing temperature. For S-PVC it was further found that slip increases with increasing pressure.
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