SOLVENT EXTRACTION STUDY ON THE SEPARATION OF MOLYBDENUM-99 AND URANIUM IN SULFURIC ACID SOLUTION BY TRI-N-OCTYLAMINE IN KEROSENE
作者:
TE-WEI LEE,
WU-LONG CHENG,
GANN TING,
期刊:
Solvent Extraction and Ion Exchange
(Taylor Available online 1984)
卷期:
Volume 2,
issue 3
页码: 435-450
ISSN:0736-6299
年代: 1984
DOI:10.1080/07366298408918457
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The basic extraction study on the separation of fission product molybdenum-99 and uranium in sulfuric acid solution by tri-n-octylamine in kerosene has been investigated. The equilibration time and the effect of temperature, concentration of extractant, uranium and sulfuric acid concentration on this extraction system were examined. The optimum conditions for the coextraction of molybedum-99 and uranium have been obtained with the overall recovery of 90% for99Mo and greater than 99% for uranium. Based on the complex stability difference between UO2(VI) and MoO2(VI) with TOA, uranium in the organic phase can be back-extracted by proper chloride concentration. On the other hand, molybedum-99 can be stripped from the organic phase by sodium carbonate or ammonium hydroxide solution.
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